You say your discharge pressure at common point on the header is 75 psiG. Your pump discharge pressures are all 92 to 96 psig. How are you losing the 17-21 psi from pump's discharge flanges to the common point?
When running your pumps individually, Pumps 3, 2 and 1 have a progressively greater suction pressure drop (relative to pump 1) at low flows. That indicates an imballanced arrangement for suction piping. You should feed into the center of the suction header, but it looks like you are feeding all pumps from the far end of the suction line and each pump draws a lower suction pressure according to their position on the header and as head losses increase down the header. BAD.
Somehow they tend to equal at around 800 gpm. There seems to be some control action going on.
Your pumps running individually all have a discharge pressure of around 90 psig at a flowrate of around 800 gpm and yet you have about the same discharge pressures when running all four pumps together. You have not explained how your system curve stays at 75 psig at the common point on the header even though you supposedly have 4 times as much flow running through it. Some unexplained control action is going on, or you have 4 pumps each feeding through separate closed loops, or maybe you are running first one chiller, than 2 chillers, then 3 chillers, then 4 chillers.
Explain your system and include a proper system diagram before you go asking any more questions. I've wasted enough of my time with this guessing game, as have other kind people above.
Independent events are seldomly independent.