Three-phase system have a definite phase sequence, either A-B-C or A-C-B. If you looked at the three phase voltages on an oscilloscope, this would correspond to the order or sequence of peak voltages (or zero crossings)for the three phases. A generator rotating in the proper direction will have a phase sequence, either positive (A-B-C)(normally) or negative (A-C-B). This is usually indicated on the generator nameplate or the generator instruction book.
The power system you are connecting to will also have a phase sequence. The generator phase sequence and system phase sequence must match. If they do not, the generator will be damaged or destroyed.
The only way to really know for sure is to do a phasing check with the generator energized and rotating at synchronous speed but **before** you close the generator breaker. There are various method of doing this, depending on your equipment, voltage, etc. With drawout switchgear, the normal method is take the breaker out, crank open the shutters covering bus and line connections and check across all three sets of phases with hot sticks and a voltage indicator. With the synchroscope at 0 degrees, you should have no voltage across each of the three pairs of breaker poles.
If you do have voltage, you will need to swap two of the generator leads and re-check. You must also make sure your synchroscope (a single-phase device) is connected to the proper phases.
Hope that helps.
dpc