Any chance you can look at it under a microscope? Even a Radio Shack $10 lighted variable power scope can do a lot of good.
We tried resistance brazing WC years ago and never could do it without damaging the carbide. What you are doing may relate to that.
Several ideas come to mind.
1. If it is standard cobalt matrix cemented WC then there is a significant difference in electrical resistivity between the WC and the Cobalt. We cover this pretty well in
U. S. Patent 5,624,626 where we use current to remove either the Co or the WC. Removing the Cobalt would leave it weaker.
2. For some reason the term eta phase comes to mind. You may be affecting the carbon and creating an eta phase embrittlement I can’t explain why but this idea seems as though it might apply. Typically this is a sintering problem.
3. I would think that a simple stress crack is more likely.
4. Maybe just forget it and try a straight chemical etch.
Our last newsletter had some good pictures of carbide defects. If you don’t get the newsletter and haven’t heard me speak lately please email and I will send you info.
Tom
Mr. Thomas J. Walz
President
Northwest Research Institute, Inc. / Carbide Processors, Inc.
3847 S. Union Ave.
Tacoma, WA. USA 98409
800 346-8274
Ph (253) 476 1338
Fax (253) 476 1321
tomwalz@email.msn.com