Is the requirement in ASTM or is it a customer specific requirement? Either way, the first thing to to is to go back to your supplier and alert them that they have material out of spec. They need to determine where the error occurred to prevent it from happening again.
You need to determine if it is acceptable. If it is an ASTM standard then you need to look at your customers to see if it is acceptable to them. If it is your own specification requirement, you need to figure out if is a problem, you should have some reasoning behind the requirement and determine if the cost for you to use it is worth the time to have replacement material.
You can have an analysis done, however, that does not trump the material test report. There are product analysis ranges in ASTM standards because of possible uncertainties in the testing methods. You could come out in spec due to uncertainties in the tests, but you still need to ensure that if the part is at the reported CMTR level it will not cause a problem.
That being said, if the difference between 0.008 and 0.009% Niobium can cause a problem you need to tighten up those specs further.