I experimented with the shiny Mylar on the OUTSIDE of a vessel today. It didn't do jack %&$!.
I think this is because, like you guys all say, it needs to go on the INSIDE where I'll get a lot more bang-for-the-buck. Also, when beyond the steel vessel wall, it's simply bouncing radiation back at the wall, heating it (the wall), and then that heat is conducted to the Mylar and out to atmosphere. It needs to be inside...
-Plasmech
Mechanical Engineer, Plastics Industry