Re "Q) Urethane melt point is above or under 250 degres celcius?'
There is no definitive answer to this question.
a) Once cured, polyurethane does not have a melting point; it will char and then burn if heated to high temperature. At 250 C in air, I think OK for short term but expect slowly degradation by oxidation over long period.
b) Polyurethane is usually formed by the reaction of 'A' and 'B' components (depends on mfr.), both liquids at room temperature. For some mixtures, you can raise the temperature of the liquid to lower the viscosity (need less solvent) and accelerate the curing rate. I am not familiar with applying heated mixtures at temperature above 52 C, but this is only general knowledge, maybe you have special type. In any case, you must have some concern that when the solvent flashes off it will leave porosity in your coating.
Some polyurethanes form by reaction of one component with moisture in air. I think this kind is unsuitable to apply at high temperature due to insufficient moisture to sustain the reaction rate.
Regardless what type of polyurethane you are producing, follow the manufacturer's instructions. Either you are experimenting or using a polyurethane I am unfamiliar with (some applicators advertise a spray on polyurethane coating with 15 seconds cure time, so maybe there are specialists that can help you).
I wish you good luck & hope you will give your results,
Ken V.