israelkk,
Temperature units °C and °F are a new feature of ver. 13. IMHO, one of the least useful new features. See Help|Tutorials|New Features in Mathcad 13. That's about the only place they are explained. I can't find them under units in Help|Mathcad Help.
To enter the new units when defining a variable, you have to use the postfix operator xf from the evaluation toolbar. You don't have to use xf when adding the units to a result in the units placeholder, though.
The units are not multiplicative. You can't use them in equations that involve multiplication and division without running into trouble. You also can't use °F as the unit for the result of adding two values with units of °F. New multiplicative units [Δ]°C and [Δ]°F are also new features. Effectively [Δ]°C = K and [Δ]°F = K·5/9.
I find it all confusing and avoid using the new units. If you violate the multiplicative rules, you get answers, but they are wrong. This is dangerous. Using the [Δ]°C units usually works, but it is the same mathematically as using K and is harder to use. About the only useful thing to do is to define a variable, say T1:=13°F, then evaluate it in °C to get the conversion T1=-10.556°C. If you start using T1 in equations, you get in trouble quickly. For instance, if you define T2:=2*T1, it evaluates to T2=485.67°F or T2=945.34[Δ]°F, not T2=26°F.
You can just type a number then type in the unit as text without typing a *. At least most of the time. I have run into cases where this doesn't work but I can't remember where.