Cesaredu,
Regardless of whether the vessels are new or not, the PRV must not be set higher than the MAWP, as rustbuster stated - see UG-134 in ASME VIII Div1.
I may have misunderstood your original question - if you are wanting to re-hydrotest existing vessels, then you would need to remove or isolate any PRVs if you are testing above MAWP - see for example paragraph 6.5 in API-510.
Cheers,
John