"We know He does not permeate through bulk metals"
Or at least not at readily measureable rates.
"but we are looking at depositing thin films of metal and it needs to seal well for He."
Different question - the permeation rate through a thin deposit will depend on the degree of porosity of the deposit. Generally, vapor deposits (done in vacuum) give lower permeation rates, but that was 15+ years ago when I was looking at it. There are lots more deposition technologies available today.