Here are some points to look at:
1. It may waste energy to run a 414barg PD pump for the 5barg process. I assume it was a small flow application.
2. If your PD pump have a speed controller, you could adjust the speed to reduce the pump discharge head.
3. Based on the required flow you needed, you may adjust the pump stroke length to set new discharge flow.
4. You don't want to overpressure the new system. If cost effective, you could install a pressure reducing valve on the discharge to reduce the pressure.
5. Also, you may want to reset or replace the PSV valve on the PD pump discharge (for system protection).
6. You may review the pump manual for the PD pump you have to see how much you could do to this pump. if any double, you should check the pump dealer for more info.
Remember, the safety first and good luck.