Normally, the PSV and its piping system are not designed for fire case but at the maximum operating Pressure and Temperature plus margin. When the system exposes to fire, the temperature in the pipe may exceed the specified design temperature. However, this can not be considered as normal operating temperature but upset conditions. The piping is derated at high temperature. However, ANSI B31.8 (if I recall it right) allows the piping to expose to an upset pressure of 20% or even 33% of its design pressure for a certain times and hours in a year. If the pressure associated with the upset temperature falls below the allowance above, the piping design is still OK.
Cheers,
TAD123