What's the pressure? Do you have a flush on the seal already? I'm confused as to the reason why the working height is impacting your material change. You should not have a problem running a metal filled carbon against TC in this service; you can run SiC if it makes you feel better. The bottom line is you will need to ensure you have enough of a vapor pressure margin inside the seal cavity to keep the water from flashing. At 100 deg C, you need at least 1.03 barg or more inside the seal cavity for vapor suppression. The 'stickiness' you describe tells me you just don't have an adequate fluid film at the seal interface. Water has excellent thermal conductivity characteristics, relatively speaking, but it is generally a poor lubricant for seal faces so you need to carefully review the entire application specifics. I've run seals with an uncooled recirculation flush (Plan 11, 13, 14, etc.) at these temperatures successfully; provided the vapor pressure margin inside the seal chamber is sufficient and the seal materials are designed for the temperature then that could be an option for you. The plan 23 would definitely help you as cooling the water down (below 71 deg C would be optimum) will prolong your seal life. Keep in mind that installing a plan 23 is not a plug and play system. You need to make sure your heat exchanger is properly mounted and you have provisions to vent the loop prior to startup. Vapor lock in a plan 23 loop is a killer for the seal. If you do decide to go with a plan 23, also keep in mind you'll need an alteration to your seal design to include a pumping ring for circulation.