Thanks for your response. I believe I didn't give the whole information required. The on/off valves are pneumatically actuated. The solenoids just control the air flow to the actuator. I understand the principles behind the intrinsically safe design. In our installation, we have intrinsically safe instruments operating at 120 VAC. I know that a solenoid could draw more current than an electronic instrument. In case of solenoid valves, I've seen them operating usually under 30V. I just needed a confirmation that they really don't (or can't) exist. It might be that they are rare/expensive but still possible to get.
Is it positive that these valves don't exist even for the small sizes?