First, you make a negative of the exposed face with the silcone. Then, you put some release agent on it.
Then, you mix up a batch of acrylic casting resin, spoon it on to the coated silicone, and keep moving the silicone around underneath it until the silicone is fully coated and the acrylic 'kicks'. You might want to preinstall some dams around the edges of the silicone to keep the acrylic from running off the negative's face.
When the acrylic has cured, peel away the silicone and you have a replica of the exposed face of the plastic part, with an irregular wall thickness, and nothing behind it.
Next, instead of trying to reproduce the back face of the plastic parts, I'd make a replica of the part of the car that faces the back face of the plastic parts, make an acrylic negative of that, and bond the two acrylic pieces to each other back to back, maybe with some urethane insulation foam between them to stiffen and bond them.
The resulting extra- thick laminated assembly could be stuck to the car with a little rubber cement on the back.
Mike Halloran
NOT speaking for
DeAngelo Marine Exhaust Inc.
Ft. Lauderdale, FL, USA