I am not a mechanical engineer, but I know that Al has been used in many PV applications. Its thermal conductivity is about 10x that of stainless steel. It is commonly used for cryogenic applications due to good ductility at low temperatures, but also often used at moderately elevated temperatures. Heat exchangers and gasoline engine pistons might also be considered PV applications.
For at least 40 years, the ASME Boiler and Unfired Pressure Vessel code has permitted the use of Al 3003 and certain other alloys at metal temperatures not exceeding 400oF.
Aluminum has also been used for steam and condensate lines in the chemical and food industries for at least 60 years.
“In the processing, packing, and storage of foods, aluminum is used for steam-jacketed cookers, tanks and vats…”
Aluminum has also been used at temperatures up to 770oF for molten sulfur.
---Corrosion Resistance of Metals and Alloys, 2nd. Edn. (1963).
Regarding alloys: 2024 & 6061 (& 7075) are heat treatable alloys. I would not expect them to be used in heated applications as overaging (of precipitation-hardening phases) would occur. E.g., the 6061 T6 temper is achieved by aging at 320-350oF.
Also, Al 2024 is a corrosion-prone alloy; for many applications it is clad with a ~pure Al skin to resist corrosion. I believe that the most commonly used Al alloy for heat exchangers is 3003, either with or without the pure Al cladding, depending upon the application. Al 1100 (99% Al) is used for heat exchangers and vessels in more corrosive environments, e.g., hot, concentrated nitric acid.