Here in the US, tile on floor slabs is handled a bit differently...
First, slabs are not usually jointed. Secondly, they are not usually reinforced enough to prevent cracks or to hold the cracks to reasonable widths. I just personally recommend it and now the contractors are starting to do it more often, mostly because of the cracking problems with tile.
We are currently working on a tile debonding failure in a post-tensioned structure.
If you don't cut in joints, the crack width is larger because of the concentration of shrinkage at the joints. Another problem is that polypropylene fibers are often used in residential slabs, thus increasing the space between cracks but also increasing their widths when they occur.
Joint patterns can be chosen so as to highly reduce the probability of wide cracks occurring under anticipated tile application (kitchens, baths, foyers)....sometimes that results in irregular joint spacing and configuration, but it works.
I recommend using a crack mitigation membrane on top of the slab and under tile. This reduces the shear transfer between the slab and the tile adhesive....probably much in the same manner as your flexible adhesive.
I see no reason that flexible adhesives would not work here as well, other than manufacturers and the Tile Council of America do not recommend them, thus putting the design professional outside a defined standard of care (thus increasing liability) if designed so. The standard is a cementitious thinset adhesive.
One problem that we encounter with flexible adhesives on floor slabs in the US is re-emulsification due to high alkalinity and moisture transmission. Non-latex adhesives would probably be fine.
As for aligning tile with joints, that's rarely done except in long, narrow applications. Though the Tile Council requires the design professional to designate joints and locations, it is not often done. Either the membrane is used or you just don't worry about it and let the tile debond if it so desires.
What are some of the brands of flexible adhesives that you use in Oz? I'll give it a shot on my own house first, to see how it works.