Compensating pressure in Cryogenic Storage Tank

[fadel_n]

Hallo everyone,
I am new here and I am working in CO2 liquifaction.
Our issue in designing the loading station lies in the rate of unloading the liquid CO2 from the Storage Tank. As my understanding and after trying with estimated calculation, for a 300 Ton Tank and with an unloading flowrate of 20 Ton/hr, I recognized that the pressure drop significantly given the initial pressure in the Tank is 14 bar (a) and temperature -31 celsius. The pressure as per calculation become 4.87 bar (I think not logical ).
In this case we are obliged to install a pressure building coil to maintain the pressure inside the Tank and prevent dry ice formation.
Can you please clarify this phenomenon and whether my calcullations were correct?
Another point need to highlight is that when we unload 20 Ton of liquid CO2 from the Tank, we need to replace this volume of liquid by CO2 gas. How can we relate the removed liquid to the gas volume to be replaced. Then we need to change it to liquid to be vaporized and maintain the pressure.
for information: I used the real gas equation (Van der Waal) and mass equilibrium equation.
Thank you for your clarification

 

[GD2]

Hallo everyone,
I am new here and I am working in CO2 liquifaction.
Our issue in designing the loading station lies in the rate of unloading the liquid CO2 from the Storage Tank. As my understanding and after trying with estimated calculation, for a 300 Ton Tank and with an unloading flowrate of 20 Ton/hr, I recognized that the pressure drop significantly given the initial pressure in the Tank is 14 bar (a) and temperature -31 celsius. The pressure as per calculation become 4.87 bar (I think not logical ).
In this case we are obliged to install a pressure building coil to maintain the pressure inside the Tank and prevent dry ice formation.
Can you please clarify this phenomenon and whether my calcullations were correct?
Another point need to highlight is that when we unload 20 Ton of liquid CO2 from the Tank, we need to replace this volume of liquid by CO2 gas. How can we relate the removed liquid to the gas volume to be replaced. Then we need to change it to liquid to be vaporized and maintain the pressure.
for information: I used the real gas equation (Van der Waal) and mass equilibrium equation.
Thank you for your clarification

OP,
If your tank operating conditions are correct (14 bara at -31C), this condition is very near to the liquid-vapour transition. A small drop in pressure will most likely change the liquid CO2 to gaseous state, NOT solid (dry-ice) (refer to any carbon-dioxide pressure-temperature diagram).
It is common that as you offload the liquid CO2, the tank pressure will start dropping as the liquid CO2 is withdrawn. The pressure drop will be faster when the tank is nearly empty.
To increase the tank pressure, a pressure building system like adding a heater is one option but you should look more closely into the filling option as other experts have suggested.

 

[LittleInch]

OP,
If your tank operating conditions are correct (14 bara at -31C), this condition is very near to the liquid-vapour transition. A small drop in pressure will most likely change the liquid CO2 to gaseous state, NOT solid (dry-ice) (refer to any carbon-dioxide pressure-temperature diagram).
It is common that as you offload the liquid CO2, the tank pressure will start dropping as the liquid CO2 is withdrawn. The pressure drop will be faster when the tank is nearly empty.
To increase the tank pressure, a pressure building system like adding a heater is one option but you should look more closely into the filling option as other experts have suggested.

GD2 I think you mean the pressure drop will be faster when the tank is nearly FULL? I.e. volume change is significant.

 

[GD2]

GD2 I think you mean the pressure drop will be faster when the tank is nearly FULL? I.e. volume change is significant.

Hi LittleInch,
When liquid CO2 is offloaded from a storage tank, the tank pressure will initially decrease due to the removal of the liquid CO2, which contributes to the overall pressure within the tank. However, as the liquid CO2 is removed, some of it will vaporize (turn into gas) to maintain equilibrium, which will then increase the pressure within the tank. The net effect on pressure depends on the rate of offloading versus the rate of vaporization, and other factors like temperature. If the offloading is rapid and vaporization is slower, the pressure will drop. If the offloading is slow or the temperature is high, the vaporization will be faster, and the pressure drop will be less pronounced, or even increase.
To maintain constant pressure, the rate of liquid CO2 being removed (unloaded) needs to be matched by the rate of liquid CO2 evaporating within the tank. This vaporization replenishes the vapor volume, keeping the vapor pressure constant.
In practical applications, pressure control systems are often used to regulate the unloading process and maintain the desired tank pressure.
The key to keeping the pressure constant during liquid CO2 unloading is to carefully manage the unloading rate and ensure it is balanced by the vaporization rate within the tank.
The rate of vaporization is influenced by factors like the temperature of the liquid CO2, the surface area of the liquid exposed to the vapor space, and the rate of heat transfer into the tank.
Dynamic simulations are often used to model and optimize the performance of CO2 transfer systems, especially during unloading.
When liquid carbon dioxide pressure drops below 4.18 bar (5.18 bar, abs) solid carbon dioxide can form at -56.6C.

 

[fadel_n]

OP,
If your tank operating conditions are correct (14 bara at -31C), this condition is very near to the liquid-vapour transition. A small drop in pressure will most likely change the liquid CO2 to gaseous state, NOT solid (dry-ice) (refer to any carbon-dioxide pressure-temperature diagram).
It is common that as you offload the liquid CO2, the tank pressure will start dropping as the liquid CO2 is withdrawn. The pressure drop will be faster when the tank is nearly empty.
To increase the tank pressure, a pressure building system like adding a heater is one option but you should look more closely into the filling option as other experts have suggested.

Thank you GD2

 

[fadel_n]

Hi LittleInch,
When liquid CO2 is offloaded from a storage tank, the tank pressure will initially decrease due to the removal of the liquid CO2, which contributes to the overall pressure within the tank. However, as the liquid CO2 is removed, some of it will vaporize (turn into gas) to maintain equilibrium, which will then increase the pressure within the tank. The net effect on pressure depends on the rate of offloading versus the rate of vaporization, and other factors like temperature. If the offloading is rapid and vaporization is slower, the pressure will drop. If the offloading is slow or the temperature is high, the vaporization will be faster, and the pressure drop will be less pronounced, or even increase.
To maintain constant pressure, the rate of liquid CO2 being removed (unloaded) needs to be matched by the rate of liquid CO2 evaporating within the tank. This vaporization replenishes the vapor volume, keeping the vapor pressure constant.
In practical applications, pressure control systems are often used to regulate the unloading process and maintain the desired tank pressure.
The key to keeping the pressure constant during liquid CO2 unloading is to carefully manage the unloading rate and ensure it is balanced by the vaporization rate within the tank.
The rate of vaporization is influenced by factors like the temperature of the liquid CO2, the surface area of the liquid exposed to the vapor space, and the rate of heat transfer into the tank.
Dynamic simulations are often used to model and optimize the performance of CO2 transfer systems, especially during unloading.
When liquid carbon dioxide pressure drops below 4.18 bar (5.18 bar, abs) solid carbon dioxide can form at -56.6C.

Thank you GD2
This is exactly what I am trying to find out a solution for. How can I balance the unloading rate and maintaining the same pressure in the Tank to prevent dry ice formation.
I have also found that during unloading in the trailers, a return hose can be connected to the storage tank which will enable the transfer of gas from the trailers to the storage tank which in turn help in maintaining the pressure. To note that before start unloading a pressure balance will be made between the storage tank and the trailer.
by doing this we can reduce the power required for the pressure building coil ( reduce the quantity of Liquid CO2 to be vaporized). However, at the same time what we get from the trailers may affect the quality of the liquid CO2 stored in the Tank.