pressure vacuum forming is used for large cosmetic appearance parts, eg. instrument housings, that plain vacuum forming would have problems with material section thinning due to draw depth. Simply, it's standard vacuum forming with slight positive pressure blown on the other side.
Vacuum (pressure) forming tools for optically clear material are polished aluminum, epoxy or epoxy with a ceramic coating.
Canopies as you describe are almost always post processing heat treated (tempering almost) and/or polished as the thermal cycling, handling and tool just about always introduce imperfections. Also, canopies are typically thicker sheet material than is typical for vacuum forming, as such poor themal conduction limits their mass-manufacturing processes. Often, canopies are hand fabricated in multiple passes using combination of drape forming and local area heat forming.
Some fabricators successfully drape form thick polycarbonate sheet for armoured vehicle ballistic windows, but the curvature is slight.