tyagimayank,
I have applied tolerances to a fair number of angled mirror mounts, so I am familiar with something similar to your problem. I am not sure how I would inspect your feature, given your tolerances.
In your latest figure, your dimensions and datums are adequate to specify geometry. Your original figure was not.
On my angled mirror mounts, the angle is very critical, and the location of the surface is much less so. I apply a composite tolerance showing a profile of[ ]0.4mm, and and angular tolerance of[ ]0.02. This means that the entire face must be located entirely within an envelope 0.4mm thick with respect to the datums. When I fixture the face at 105[°] using datums[ ]A and[ ]B, I should see a variation in the surface of no more than[ ]0.02mm. Note that flatness is tightly controlled, even though I did not call it up.
I would interpret your positional tolerance as something similar to the profile tolerance, but you have not imposed controls on the shape of the feature. The mean, central position of the feature could be within your[ ]0.05mm, and the feature could be out of flat by way more than[ ]0.05mm. I do not think your positional tolerance controls the angle. Your figure would make more sense to me if you specified flatness, and applied a tolerance to your angle.
JHG