I should have mentioned before - when I said that I had only seen 3 references to autogeneous healing of concrete, I should have said specifically "in relation to the definitive calculations for the autogeneous healing in a concrete tank".
There has been quite a few references in German (I don't speak the language) & also in other publications relating to the healing process, generally.
For a general view of the subject, have a look at: -
A M Neville, “Autogenous Healing – a Concrete Miracle?”, Concrete International, November 2002, pp 76-82.
I pinched this next reference from the Nov07 copy of "Pipeline" from the Conc Pipe Assoc of Oz"
Necessary conditions for autogenous healing
In a recent review, Adam Neville3 summarises literature having a bearing on conditions necessary for autogenous healing of cracks. At an early age, continuing cement hydration in which calcium silicates in the cement are converted to calcium silicate hydrate can play a direct role in the healing process.
In cracks healed at a later stage in the life of a structure, the main product which fills the crack is calcium carbonate, formed by combination of calcium from the hydrated cement with carbon dioxide dissolved in water from the atmosphere or other sources. Neither water hardness nor pH has been found to influence the process of autogenous healing. Various investigators have reported different maximum widths at which cracks have healed – “not surprising because the test conditions have varied widely. In some cases, the cracks were caused by shrinkage, in others by the application of tension, usually flexural but in some tests by direct tension. The age at the opening of cracks varied too. The healing took place in static water or flowing water. There was a head of water or not. The water was fresh or seawater.”
Among examples reported are reinforced concrete pipes that developed shrinkage cracks up to 1.5 mm wide, and were subsequently put into service. Five years later, the cracks were found to be completely closed by autogenous healing.
Hydrated cement is partly soluble in water4, whether or not there is carbon dioxide present. Carbon dioxide dissolved in low concentration from the atmosphere plays a role in the healing process, precipitating calcium carbonate, but is not necessary to initially dissolve calcium from the cement. Autogenous healing will take place unabated in concrete made with blended cement, even though such concrete may be found not to contain any “free lime”. Roberts5 confirms that the type of water and the cementitious material have minimal effect.
For reinforcing steel to corrode, moisture must be present both for its part in the chemical reaction at cathodic sites on the steel surface, and to provide a conducting path through the concrete for the electrolytic current. If the concrete is cracked, the same moisture provides a condition for autogenous healing. Initially, the environment at the root of a crack may be favourable to steel corrosion, particularly if the water contains chloride which breaks down the passive film on the steel. Some rust will be formed, occupying a larger volume than the original steel and perhaps tending to disrupt the surrounding concrete. However given an ability on the part of the concrete to resist such disruption, autogenous healing will progressively restore a situation in which the corrosion is unable to continue. Calcium hydroxide, silicates and carbonate will be deposited in the crack, on the surface of the steel and in the pores of he rust. Of the two competing tendencies – disruption by rust, or isolation of the steel surface, assisted by autogenous healing, circumstances will allow one or the other to predominate.
I have his book at home, on cracking in concrete. He has published many articles on concrete over the years.