For interesting stuff on unusual poisson's ratios, check out
. This is mainly about negative poisson's ratios ('auxetic' materials), and includes instructions for home manufacture of metal and plastic foams which have negative poisson's.
For a 2D "material" like a sheet of honeycomb core, for hexagonal cells the poisson's ratio is 1.0 in both the 12- and 21-directions. If you stretch the core sideways ("over expanding" it), the cells become more rectangular. When the cells are exactly rectangular, the theoretical poisson's ratio is 0 in the 12-direction and infinity in the 21-direction... For a cell shape which deviates from rectangular (90 degree internal angles) by 5 degrees the theoretical 21 poisson's ratio is about 10.5. It's similar at the other extreme: for "under expanded" honeycomb cells, with internal angles 90, 135, 135, 90, 135, 135, the 12-direction theoretical poisson's is 2.41 (actually root(2) + 1). For completely unexpanded core the 12-direction poisson's is infinite while the 21-direction is zero. I have a little Excel 97 spreadsheet illustrating honeycomb core poisson's ratios for different cell shapes that I can e-mail you if you post an e-address.
It is also possible to manufacture 2D "materials" like this with very large negative poisson's ratios. You have to manipulate the cells so that they all become sort of 'X'-shaped.
All these effects rely on the "material" having a microstructure (macrostructure, really, in the case of honeycomb core) which behaves as a mechanism. 3D materials are possible, but get more complicated. Coming up with what we would regard as actual materials with such properties is trickier. I remember an article in Nature in either 1993 or 1994 which featured negative and unusual poisson's rations in single-crystal metallic materials. However, from memory the poisson's were highly anisotropic. More recent stuff can be found from entering auxetic into the search box at
.
There's also some fascinating stuff about materials with a phase having negative stiffness at
, though for "with a phase" something like "including micro-mechanisms" might be more appropriate.
Thought for the day: if you mix equal amounts of positive and negative stiffness "materials" together, the flexibilities cancel out and (for just an instant) you have something with theoretically infinite stiffness...
-R.