I will assume you are referring to the inside rolled cope of the beam where the flange and web come together. Other than access to achieve a good quality weld, no. The weld profile will be odd for two reasons...you are likely to leave inclusions on the back side of the plate unless you miter the plate to its back side, leaving no land. The opposite edge of the weld would be made against the coped surface, making the weld section tapered in thickness. I doubt that this profile would be pre-qualified, so to meet US code, you would have to qualify a welding procedure specification for this.