[Why would you want to place the electric heater inside of the pressure vessel ?
This makes heater maintenance and eventual replacement difficult and dangerous, IMHO/quote]
Flanged electric immersion heaters are used for heating and vapourizing flammables all the time. There's nothing inherently more hazardous about using or maintaining them than any other type except perhaps a FIRED heater, which of course is far more hazardous- but those are used for flammables to, on a gigantic scale.
If your choice is between building a new heating utility (steam, hot oil, Dowtherm vapour etc.) for one or two users or using electric directly, and the duty is modest so the energy consumption isn't a huge cost issue, the selection is a fairly easy one.
You can put the heating element on the outside of the heater shell if you only need a tiny amount of surface area and you don't care about surface metal temperatures. With a propylene vapourizer, that's not likely to be the case.
If you're really worried about heater surface temperatures, and your energy source is ultimately electricity, then you need an intermediate fluid- something like hot oil or Dowtherm vapour.