Suggestion: Traditionally, circuit breakers used lower ampacity rating at higher rated conductor insulation temperatures, e.g. 75degC ampacity rating of 90degC conductor insulation thermal rating for circuit breakers over 100A rating and 60degC ampacity rating for 75degC conductor insulation rating. Up to 100A C/B 60degC conductor insulation is often used. Some c/b manufacturers offer 75degC circuit breakers for any frame. The reason for the lower temperature of conductor insulation or ampacity rating is that the elevated conductor temperature might affect the thermal magnetic circuit breaker tripping.
Depending on the circuit breaker terminal thermal rating, the corresponding cable lug thermal rating should be used.