Well, you have two (or three or four) possible problems here.
one. If you have one TC, you know what the temperature is at that TC during the PWHT cycle.
If you have two TC's, you are no longer sure which one is correct (or =- since both might be wrong - which one is closer to the real temperature).
two. If you have a TC on the surface, you are only estimating what the real temperature is inside the steel, several inches (CM's) away from the measurement point. The longer the soak time, the slower the heatup rate and cooldown rates are, the better the insulation is around the TC, the further the TC is from the heat source and any cool zones, the better your assumption will be that the actual center-of-steel-temperature is compared to the surface-of-steel-temperature-under-the-TC.
three. You can probably assume that the surface temperature between any two or three TC will be close to the distance weighted average of the average of the two (or three) TC's. But steel-inside-the-PV-wall temperature will never be the "perfect average" of any two or three surface temperatures.