Let me be a bit of a contrarian here. It sounds like we are all assuming that the best coating for the outside is a reflective one. (I sort of think so too, but read on.)
I am not that familiar with switchgear, and even less so with Australian nomenclature for same, but it sounds like you have a heat producing element in a vented box that is inside an outer vented box. The rest of my comments are based on this.
Consider: it is said that the Bedouins who wear black clothes are actually cooler than those wearing white because the hot clothes create an enhanced chimney effect.
Also consider: in addition to the solar heat loads in question, there is the internal heat load of the power equipment. If this is significant, then a high emissivity coating may be more desirable for increasing the heat rejection of the internal heat, than a reflective coating's rejection of solar load.
An FEA or CFD model, including the transients of solar load and the chimney configuration would be an appropriate way to look at this problem.
Of course if the internal heat load is very low then its rejection becomes unimportant. The chimney effect is still in question however. (and why put that type of structure in if the internal is very low)
richvanger1 suggests a primer to reduce emissivty. It is my understanding that a primer would not be effective if there is another coating over it. The top coat's properties would govern.
If it proves that low e is good, then you might still use dark green with aluminum flake dispersed in it, or another low e approach. (Just watch out for the glare! ;-))
I have done some models along these lines in FEA. They can be quite informative. Some samples are on my website, if you are interested. Jack M. Kleinfeld, P.E. Kleinfeld Technical Services, Inc.
Infrared Thermography, Finite Element Analysis, Process Engineering