Here's what the 2002 NESC has to say on the subject, complete with bad grammar:
A safety sign shall be displayed at each entrances. For fenced electric supply stations, a safety
sign shall be displayed on each side.
NOTE:
ANSI Z535.1-1998, ANSI Z535.2-1998, ANSI Z535.3-1998, ANSI Z535.4-1998, and ANSI
Z535.5-1998 contain information regarding safety signs.