Dave,
Colour pictures are not the answer, as colour is not what you are looking for in spark testing. It is structure:
the lace and arrows and fineness of the spark pattern. The primary element you'll sort for is carbon. The rest of the metals are much harder to see, if at all. Low carbon steels have almost all straight sparks; high carbon is almost all lacy bursts.
As unclesyd says, keep the wheel clean. As swall says, the ASM metals handbook has info - better still find a very old edition. Spark testing has fallen from grace in the computer-in-your-hand era. But it has its place yet.
Wear protective goggles or shields. Keep the light low. Use a gentle touch. The volume of sparks results from how hard you bear down on the wheel - not the chemistry. This is an inexact art and requires practice. But for rapidly sorting between two suitable unknowns, it is priceless.
There are also various 'spot' tests which use chemical reagents. A bit messy, but useful too sometimes.
For plain carbon steels, a good eye can distinguish 20 points. Almost anyone can tell 50 points or carburized from not. Many tool steels have quite unique spark signatures - develop a known sample box and practice, practice, practice.