cef2003
I am not exactly clear how your system is working. You have effluent from a building discharging to two septic tanks in series. The discharge from these tanks goes to an Ecopod (?? you will need explain what that is as a google search throws up something which looks like a greenhouse) which in turn discharges to a third (existing) septic tank.
At the top of the sewer line at your building you should have a soil vent pipe (SVP). This allows any gas build up in the sewer to vent to atmosphere. And because your pipe invert level increases the closer you are to the building, all gas in the pipe should vent there. That said, a lot of sewer gases are heavier than air.
However, the invert of the pipe entering the tank is not at the top of the tank, so any gas above the crown of the pipe needs to escape somewhere (as it cant go up your inlet pipe).
Also you dont want the situation occuring that when someone opens the cover they get gases escaping in their face, not nice (CO2 displaces oxygen but is heavier than air, H2S does the same and is also heavier than air, and CH4 is flammable and lighter than air).
But, in practice this is rarely an issue. Most septic tanks come with light duty plastic covers which will vent any gas to atmosphere. It is only a concern if you are replacing these with heavy duty sealed covers.