virgil1961
Chemical
I am working on design for high pressure and high temperature process. The problem is defining the design temperature for a piece of piping between a high pressure (4300 psig design pressure) and high temperature (design 1100F) reactor and downstream exchanger (design temp 750F with design pressure of 4300 psig). The normal operating temperature at the exit of the reactor is 300 to 500 F. However, should the quench water stream that enters into the bottom of the reactor fail, then the exit temperature of the reactor will be as high as 1000F. The piping spec. currently calls for an expensive high nickel alloy for this piece of piping (4300 psig @ 1000F design T and P).
However, there is limited corrosion data on this alloy material for this service, and that data available shows poor performance. Some people on the project dont' want to use extra thick or bigger piping for this service due to cost issues with the piping (length of piping is about 15 ft). Therefore there is a push on the project to change this material to C276, which has demonstrated more favorable corrosion resistance. But the problem here is that the temperature rating for C276 goes down to 750F which is lower than the worst case temperature excursion (to 1000F, some people want to ignore this case saying it's only for a minute or less and they want to measure the temperature with redundant thermocouples and replace the piping when that temperature is exceeded, other people are saying no, it can be as high as 5-10 minutes due to operator response time and one can not depend upon the TCs because they are controls and not a mechanical device). I could not find a mechanical device that could be put into the piping that would activate at 750F in event of thermal excursion to higher temperature (>750F). The C276 fails to meet code requirements, yield and stress fails, at these higher temperature excursions (>750F).Please advise on approach to setting piping design temperature, thanks!!
However, there is limited corrosion data on this alloy material for this service, and that data available shows poor performance. Some people on the project dont' want to use extra thick or bigger piping for this service due to cost issues with the piping (length of piping is about 15 ft). Therefore there is a push on the project to change this material to C276, which has demonstrated more favorable corrosion resistance. But the problem here is that the temperature rating for C276 goes down to 750F which is lower than the worst case temperature excursion (to 1000F, some people want to ignore this case saying it's only for a minute or less and they want to measure the temperature with redundant thermocouples and replace the piping when that temperature is exceeded, other people are saying no, it can be as high as 5-10 minutes due to operator response time and one can not depend upon the TCs because they are controls and not a mechanical device). I could not find a mechanical device that could be put into the piping that would activate at 750F in event of thermal excursion to higher temperature (>750F). The C276 fails to meet code requirements, yield and stress fails, at these higher temperature excursions (>750F).Please advise on approach to setting piping design temperature, thanks!!