Hi ScottyUK
With all due respect you are wrong, sir!
First of all the jacket is made of PVC –power cables mainly- due to other properties of PVC as mechanical resistance and flexibility-but there are other materials as hypalon, chloroprene[neoprene] , fire-resistant non-halogeneted materials and other. The XLPE insulated core has no problem with humidity for low and medium voltage cable.
For high-voltage cable, longitudinal and transversal water barrier [moisture barrier] is provided. PVC moisture resistance is low-not so low as polyamide [nylon] but still low.
Also the permittivity factor is high[ 7-10] and the tang.delta too. This material is indicated nor for telecommunication cable as dielectric attenuation is high neither for medium voltage cable.
In the old good time the telecommunication cable core was paper insulated and lead sheathed. All the electrical properties as capacity and capacity unbalance was very good and for long time.This cable was very expensive .So the polymer used to be employed instead.No cable –for long and medium distance –was insulated with PVC except switchboard cable-short length and in dry location.For outside location the cable was insulated with LDPE[Low Density Polyethene] namely foam[cellular]and as the PVC jacket was not moisture barrier a sort of Petroleum Jelly used to fill the air gap between core and jacket.After a while, a moisture barrier of longitudinal applied aluminium foil, both side poliethene covered was employed, so PJ was not required yet and the core was insulated with solid HDPE[high density poliethene-as LDPE seems to be carcinogene].Up today telecommunication cable insulated PVC is limited for dry location and limited length.
By the way, the signal attenuation for 100 Khz or 1000 Khz does not seems to differ.
Best Regards