There should be a diagram in the tables that says.
In some cases, "a" will always be the longer dimension, and you'll have tables of a/b or b/a that don't extend beyond 1.00.
In some of the Roark load cases, there will be a section defining all the variables, etc., then tables of different load cases, and you may need to refer to that section.
Don't confuse the circular-plate tables with the rectangular plate tables.
If that doesn't help, let us know which edition of Roark's, which table, which load case, which page, and maybe somebody can look it up.