If you think about concrete, it expands, just like gas.
A perfect structure would be a sphere, like a basketball.
Well, since we can't design with spheres, there is always a trade-off of a combination of spheres and rectangles and triangles/etc.
Where is the pressure being applied? (Concrete acts the same as wood or any other material) If the pressure is applied on the side, it would emulate and arch or square. If the pressure is applied on the top, it would practically be identical, unless it is convex or concave at the top.
Other things, though rarely considered are outside forces.
Say you have pressure one 2 sides, rather than just one side?
All in all, I would have to go with the cylinder.
It emulates a arch, which is the strongest ????, but again, it is all where the pressure is applied.
Regards,