cm3,
the question about readymixed concrete is not phrased in a way which allows for a definite answer. The fact is that properly batched concrete is necessary, whether this is achieved by the contractor by using his own on-site batching plant or by using an off-site readymixed concrete supplier is his choice.
There is no spcific requirement for an additional 10% cement for a tremie concrete mix. Many large piling projects now use pumps and a mortar mix is used first, this mortar is of course discharged away from the pile.
Bentonite or polymer (or a mix of the two) will often be used as excavation support. Depending on the specification the pile may typically have to be completed within 12-24 hours of excavation. The actual time for placing the concrete will vary according to the size and depth of the pile, 100m+ is not unusual.