A good reference for this issue is the Caltrans (State of California) Shore Protection manual that you can download on-line.
Although as many posts have noted, 2:1 has become the standard for ungrouted rip-rap, we have had several projects where environmental agencies have conditioned no grouting, and economics have prevented walls. Select placement of the stones to decrease the voids and create effective point-to point contacts will allow steeper slopes. But a larger skeleton size (i.e larger stones), within intermediate filler sizes will be required, with good field control.