Hwa is thet mei thet hors wettrien the him self nule drinken
When the fluid velocity is low; (1) the air bubbles will not move down the the pipeline and (2) the air bubbles will create additional headloss because the air bubbles are effectively narrowing the pipe diameter. Your fluid velocity is only 2.6 ft/sec which is low (1.5 liters/sec flow in a 48.5 mm ID pipe).
A low flow condition is the same as a zero flow condition. The air will simply not move down the pipeline no matter how many air release valves you install.
You have said the HDPE pipeline is DR11 which means it is typically rated for 13.8 bar working pressure at 80 Degrees F. DR11 HDPE pipe has an ID of 48.5 mm. (You should confirm with the pipe supplier).
13.8 Bar - 64 meter static head - 20 meter service static head = 8.2 bar available for pumping head (83.6 meter of head). So you have 83.6 meters of head available for pumping.
If you do not overpressure the pipeline, you are only able to pump 1.45 liters per sec.
If you attempt to pump at a higher flow rate, additional pressure will be necessary from the pump to force the water through and you will overpressurize the lower reaches of the pipeline.
Pumping 1.8 liters/sec for 6 km will result in 125 meters of head loss.
Pumping 3.0 liters/sec for 6 km will result in 322 meters of head loss.
Check the calculations yourself with the online calculator:
You need to determine the water demand, recalculate the water pump requirements, replace the incorrectly sized pumps, and replace the pipeline with one that has the proper pressure rating.