Does the pulley have four drive belts, all the same size to give enough torque capability, or is it a step pulley with one belt to give a range of speeds? The step pulley is easier to find off the shelf, although you'll probably have to modify the bore/Keyway to suit your shaft. Also try searching for Vee Belt Sheaves.
If you can't get what you want in one piece, you could stack individual pulleys and bolt them together.
To machine them from the solid, you'll need a fair sized lathe with a rigid set-up or chatter will be a big problem (especially with a plunged form tool where you may even have to resort to hand pulling the pulley round to clean out chatter as a last resort)
Machinery's Handbook show drawings for the groove profiles in the popular belt sections.
I found this online a few years age when I had to make a special, but I cheated and used a CNC lathe to avoid the form tool problem:
Trevor Clarke. (R & D) Scientific Instruments.Somerset. UK
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