In my view, the consideration of the phenomenon labeled buckling comes to attention as contributor to the ruin of a member or plate.
The example I put, valid as well for post-tensioned beams wich excessive prestress is not customarily labeled a buckling case because we are normally dealing with beam behaviour that we try to favorably modify trough prestress.
Yet in any case and compared with what we have in a doubly pinned buckled column, we have
same kind of curvature (buckled shape)
eccentrical compression (under compression)
failure either in the compressive or tensile side
and stating that this is not buckling may be accepted under the need to agree on some terminology, but not respect the similitude of the kind of failure where it occurs.
This mode of failure of course is normally prevented by mere care in fabrication and prestress transfer, but may develop if unawarely concrete of deficient stress is prestressed or post-tensioned.
Respect gain on buckling load being moderate, well, in about that is in what the question at some moment turned unto, and again I think it would be more proper to re-state the question on if one would be able to meet a higher load than without the prestress, and it is obvious that there are situations where such is the case, out of mere growth of standing inertia of the section or of direct clever counteraction of some otherwise clearly predominating mode of failure.
On the other hand, for very slender elements except great care is exercised in the position of the prestressing elements, even with moderate prestress one can even get accidental tensile action from prestress, and this will be detrimental where the estochastically variable orientation of the buckling under the loads or simply the flexure induced by the end boundaries' forces sums initial tensile stress to such tensile action, and initial compressive stress to the compressive action. In this case the initially locked prestress, even moderate, turns out to be not favorable.
And similar considerations can be made for short-columns if unreasonable tolerances on eccentricity are allowed.