An exact derivation would be a tough math problem based on a triple integral in cylindrical coordinates. An ASME S.E. head is not a perfect ellipse, so you would need to come up with some complex formulas for your boundary conditions...
If you are just looking for close enough, I think there are good formulas for determining the volume of an ellipse based on the two radii.
When asked, I actually find it a whole lot easier to whip open solidworks and model the head. It takes less than 5mins, and I would feel a lot more comfortable with the results.
Good luck!