I don't see Ca as a means of making meaningful fluid comparisons. The only fluid properties that enters the equation are Vapor Pressure and Density, so other than a ratio comparing volatility to density, there doesn't appear to be anything else that you can derive from the Ca number in regards to comparing fluids to one another.
It may serve to compare the ability to pump fluids at low pressures, but I don't see the need for that either. In the real world, you seldom if ever get any choice between fluids that need to be pumped. You either have to do gasoline today, or diesel today, or visa versa, and usually you have to be able to pump either one.
But Ca describes the ratio of Net Positive Suction Head, Suction Pressure - Vapor Pressure, to velocity head, rho V^2/2/g which could be useful knowledge when designing a pump system.
Suction Pressure - Vapor Pressure can be thought of as your operating suction pressure's margin of safety against cavitating conditions. The "Cavitation Number" compares that margin of safety to Velocity Head, 1/2 rho V^2/2/g
When calculating Net Positive Suction Head Available, NPSHA, for a pump system, usually velocity head is ignored in order to arrive at a conservative calculation for NPSHA, but velocity head can be included in the NPSHA calculation, if the system designer feels it is warranted.
So in the usual case where velocity head is ignored in the NPSHA calculation, the Ca number would then compare the margin of suction pressure's margin of safety against cavitation to the velocity head that really is there, but was not considered. A Ca of 1 would indicate that the cavitation margin is comprised of 50% pressure head and 50% velocity head, which is kind of like a safety factor of 2 against cavitation, since you have a pressure margin against cavitation equal to the velocity head's margin of safety against cavitation. A Ca value close to 0 would indicate that suction pressure is nearly at vapor pressure and the only thing preventing immenent cavitation is the velocity head.
For your connection problem, I think I'd tend just to look at absolute connection pressure ratioed to the fluid's vapor pressure as an indication of its flashing characteristics. 1 = Flash
Maybe somebody else knows other instances of where Ca could be useful, (evaporation rate of light or heavy coatings???) , but I don't.
“What I told you was true ... from a certain point of view.” - Obi-Wan Kenobi, "Return of the Jedi"