The other thing not being addressed is the "physical thickness" and the physical properties (compression, wear, cutting, resilience)of powder coating layer. Compared to the very stiff, very thin (a few mils) thickness of a primer + paint, or the slightly thicker primer + 2-part epoxy coating, a powder coat finish can be 30 to 45 mils thick. Sometimes, but not often, even more if the coating isn't carefully applied or drips before hardening.
When compressed by the bolt force between a plate and the beam, this thick of a plastic layer will act more like a soft rubber gasket or sponge and deform and compress. There will be less - but not zero - friction force between the two structural items; and so the load between the two will carried by the shear force of the bolts compared to the high steel-to-steel clamping force usually found in structural joints.
Don't be surprised if assembly and sliding (or wedging) forces damage the powder coat either. Crane lifting? Forklifts? Truck shipping and simple pallet movement and part-to-part vibration and scrapes need to be avoided. Hate to say it, but powder coating really is a very fragile finish compared to what steel erectors usually use - which is primered and painted raw steel that they expect will "always be refinished."
Usually, I find that 1/2 - 3/4 inch of a powder coat finish is completely destroyed (MUST be destroyed!) by the heat of the welding. As mentioned above, at least this much needs to be cleaned/removed before welding to avoid contaminating the weld with the melting/burning plastic. Beyond that, about 3/4 to 1 inch of the plastic will be heat-damaged, softened, distorted or discolored. You can buy commercially "overspray" or powder coat look-alike repair "paints" but they are difficult to use, and look like what they actually are: a shaky-looking repair job.
Typical sequence: Build it and fit it and tack it in a jig. Weld up completely and inspect (dye penetrant or mag particle, visual inspection at a minimum.) Move to the powder coat spray booth/oven, or ship off site to the powder coat contractor. Coat it, return it, attach rest of the parts, ship it.