bones -
Is the problem just high temperatures (arid climate) or a combination of heat and humidity?
How big is the slab?
You perceive your enemy to be the high air temperature, but he real situation is the temperature of the concrete prior to and after placing, and controling the release of the moisture necessary for the proper hydradration of the cement.
If the slab is not too big, protection of the concrete surface from the sun does wonders and a temporary tent cover is really quite economical and effective. Everyone knows what direct sun can do to cause high surface temperatures (race tracks can easily hit 140 degrees with and air temperature of 80 degrees and no heat of hydration generated by the curing cencrete).
If it is a large slab, misting is a good way of offsetting the effects of the sun and reducing the moisture loss, but it can be difficult to control depending on size, wind and weather conditions. Covering with poly is also effective, but can effect the visual appearance.
The first step is using the right mix at the coolest temperature reasonable and place quickly. Unfortunately, cool concrete still has to cure for proper slab finishing. After that, it just is a combination of protective measures that are apprpriate for that size project.
Dick