Please don't try to pneumatic pressure test, either positive or negative, large API storage tanks with anything but water. I know of 4 deaths with pneumatic testing shop and site built API tanks. I have seen the smaller variety round the bottom out when tested with N2 instead of water, not anchored properly and few extra inches of pressure.
We always try to work around any pneumatic testing as such with such as jacket piping where Therminol Vapor is involved and water is very bad. A new pipe spool is heat cycled to our cleaning temperature and then the core pipe is hydrotested to the proper test pressure and the Therminol jacket is test with helium at 40 psig, normal hydro would be 125 psig, and sniffed. All jacketed components are He tested after the thermal burnout and bead blasting. After assembly the whole system is put under house vacuum and the decay cannot exceed 1# in one hour. If there is and indication of a leak that section is put under 25-35# He and some goes looking.
One some very large systems that operate at 150 psig prior to the introduction of the process, air and cyane, we pressure up with N2 to 70 # and watch the pressure decay. The leak rate allowed is based on an equivalent amount of Cyane vapor.
Even equipment design for high pressure air like Scuba Tanks require safe guards in filling and testing. Early on in development of Diving as recreational sport we had local dive boat that had several of the small surplus compressors used to fill tanks while traveling. One of the tanks ruptured and made the boat itself a popular dive site for several years afterward. You never know what’s going to happen.
No matter what you are testing or operating keep your hands in your pockets and not feeling for leaks. Embolism from gas, water, or oil to the extremities isn't a very pleasant sight.