You can place the dead load reaction on the cap. However for the live load, you need to look at various combinations of loaded lanes. For instance, one loaded lane may produce the more extreme effect (reaction) on a girder than if two lanes were loaded. Keeping this is mind, the HS20 truck also "floats" in its lane, therefore you may need to look at it at the side of the lane, middle of the lane, etc. If the live load reaction you have obtained is via hand, then you will need to perform the above procedure. If the reaction is from a computer program that uses influence surfaces, such as a grillage analysis, then you may be able to use that reaction depending whether the program "floats" the design trucks. One has to know the limitations/assumptions of their software.
Shorter said, is the live load reaction you have obtained from hand calculations or from a software program?