Commonly, the actual performance characteristics of an individual production pump may vary from the published generic performance characteristics for the pump model by as much as 10%. Most pumps will perform closer to the generic performance characteristics, but it is best to allow for reasonable margins for variations in the design and selection process. The criticality and potential hazards associated with the particular application weigh heavily on the margins that may be tolerable. I agree with others that this may be a tolerable selection, but the obvious increase in the NPSHr curve suggests that an uncomfortable situation may be reached very close to the chosen operating conditions. Unless there are compelling reasons to accept this situation, I would seek a more conservative pump selection.
Where generic pump performance curves are being used, I think it is best to presume that operation at or near the ends of the published curves should be avoided whenever possible. The ends of the curves may simply represent the end points of testing, but they can suggest the development of operating or durability problems beyond those points. Usually, the ends of the NPSHr curve is the best guide to the tolerable operating range for a particular pump.
Commonly, the published performance curves are based on a constant, synchronous shaft speed (1800 rpm, 1500 rpm, 3600 rpm, etc.), and the actual installed performance characteristics may vary according to the actual slip of the driving motor. While these effects are typically minor, this may not be a trivial matter when the chosen operating point is close to the ends of the published curves. This is yet another reason that I would want to avoid the selection that you are considering.
Valuable advice from a professor many years ago: First, design for graceful failure. Everything we build will eventually fail, so we must strive to avoid injuries or secondary damage when that failure occurs. Only then can practicality and economics be properly considered.