Hi, quark:
I wanted to make a couple of clarifying remarks about your earlier post of 25 Jul 05 12:40 and am sorry I was late getting back from another assignment.
It seems that some of the discussion in this thread is becoming clouded by consideration of dynamic (i.e., transient) phenomena versus the steady-state analysis that was in effect in earlier portions of this thread. The following comments are in order:
(1) LIQUIDS BELOW BUBBLE POINT TEMPERATURE
In the situation where a fluid BELOW its bubble point temperature is being pumped, the reservoir pressure is, by definition, higher than the vapor pressure and the vapor space must contain light gases whose partial pressure makes up the difference between vessel pressure and fluid vapor pressure. This difference provides a positive NPSHa. The net NPSHa at pump suction is somewhat lower, however, because of friction losses. In this situation, increasing reservoir pressure will increase NPSHa, by an equivalent amount, for a fixed system geometry. Doubtless, it is this experience that leads novices to suggest the same solution for saturated liquids.
(2) SATURATED LIQUIDS
Let us now discuss the "normal" situation where a saturated liquid (i.e., one at its bubble point) is being pumped. A temporary worsening of the NPSHa would result from a sudden REDUCTION in reservoir pressure, and would likely result in bubble formation at suction and, possibly, pump cavitation as long as the flashing liquid has not come to the new equilibrium temperature corresponding to the lower reservoir pressure.
However, a low NPSH problem CANNOT be corrected permanently simply by INCREASING reservoir pressure. Anyone who thinks this is just plain wrong. This is because there would be only a temporary increase in NPSHa caused by any increase in the vessel pressure without a corresponding instantaneous increase in fluid vapor pressure. This dynamic transient would disappear, pretty quickly in most cases, as the fluid temperature reached the new (higher) equilibrium value. At equilibrium, the vessel pressure and the fluid vapor pressure would again be equal - since we are talking about saturated liquids - and the NPSHa would be back to its old, lower, value. The ONLY exception to this general statement would be when fluid friction is a strong function of fluid transport properties (mainly viscosity). Normally, in fully developed turbulent flow, while reduced viscosity increases the Reynolds number, this does NOT reduce friction factors significantly.
Therefore, for boiling liquids, I think we can all agree that (a) decreasing vessel pressure is counter-productive, and (b) increasing pressure provides only a very short-lived improvement if you are suffering from inadequate NPSHa. The latter "solution" is advocated mostly by those who do not understand these fundamentals.
(3) GASES DISSOLVED IN LIQUIDS
For liquids that contain dissolved gases, the cavitation problem depends on how much gas will be evolved as pressure is lowered as a result of (a) friction losses, and / or (b) from hydrostatic head reduction, in case the pump suction is above the level in the reservoir. As noted by me earlier (24 Jul 05 20:07), the Henry's constants for gas solubility in most solvents are very small. For example, for air in water, the Henry's constant varies between 5.49E-4 and 10.8E-4 atm/mole fraction between 20-90 deg. C (Page 2-125, Perry et al, editors, "Chemical Engineers Handbook", 7th ed., McGraw-Hill 1997). Unless the air-water mixture is at hundreds of atmospheres pressure and so contains a large amount of dissolved air, it is hard to see a problem with cavitation unless the difference in elevation between pump centerline and reservoir level is inadequate or (hard to imagine in such a case) the pump is located much above the reservoir.
Generally, it takes very high pressures to dissolve significant amounts of gases in liquids. An example from petroleum refining might be hydrogen in hydrocarbons at 3000 psia or more. Another might be a concentrated ammonia solution, where much gas dissolves thanks to electrolytic ionic equilibrium. However, such situations are unusual and require very careful engineering.
Again, these thoughts are contributed with the hope that they will help clarify the fundamentals of the phase equilibrium problem and the issues raised by consideration of transient phenomena.
I wish to extend my thanks to all for their reflections and shared experiences.