OK. When you have access to good data, you don't have to add any margin to the expected maximum temperature.
But, in this case, the maximum temperature of operation is the design temperature. Considering this maximum temperature operating is the temperature at which, under the coincident pressure, the greatest thickness or highest component rating is required in accordance with para. 301.2. (In some cases, the design temperature is not the worst case temperature. But, in this case, the design temperature is the worst case temperature.)
So, when you don't have access to good data, you have to add any margin to the expected maximum temperature. However, in Appendix S, the stress range is calculated with the maximum operating temperature without adding a safety margin. But, the maximum operating temperature + 50ºF is the design temperature.