Nitrogen filled vessel

[REGRUMBLE]

We have a large vessel that the engineer wants cleaned and shipped with 5 PSI nitrogen. Does anyone know of a procedure to purge and fill the vessel so that we can guarantee it contains nothing but pure nitrogen.

 

[unclesyd]

it will be extremely hard to get to 100% N₂ in any vessel or tank. If the vessel is capable of weeing an external pressure of 15 psig the one would pull a vacuum and introduce N₂ to 1 psig. This is would have to repeated several times to get the purest N₂. To do this one has to use dry N₂.
My i ask why pure N₂ is required?
How large is large?
With this information there might be a better, faster ,cheaper way.

 

[jtseng123]

just do it, not a problem. I just have a large vessel shipped from Korea to south America, 5 psig N2 purge. the size: 25'-6" diameter x 100 ft T/T. They have to continue purging for several hours to expel all air out. But to prove it is 100% N2 inside the vessel, may be difficult. Vendor can do what they can do, especially for large vessel. If you are buyer, just ask vendor to provide proceudure, they will give you one. But if you are supplier, well, I have no help. You may need to define how many hours to purge.

Below is what we request:
A. Seller shall provide a nitrogen blanket on the vessel during transportation with a positive pressure of 5 psig. Shipping blind flanges, bolting sizes, and quantities shall be designed to meet this pressure requirement. A positive pressure must be maintained in the vessel throughout shipment using nitrogen cylinders and pressure regulators.
B. Welding grade nitrogen (99.9%pure) shall be introduced at one end of the vessel and the exiting gas at the opposite end of the vessel.
C. At least one connection with valves, piping or tubing, pressure gauges and nitrogen bottles shall be provided at each end of the vessel for purging and nitrogen filling.

 

[TD2K]

I'd be tempted to pressure purge it. Add in the N2 at one end, pressurize it and then depressure it through a vent at the other end. Several cycles should be enough.

Usually, a N2 pad is specified so that a) the vessel is dry and b) no oxygen is present so the risk of corrosion is greatly reduced. If you go through a few pressure purges given that nitrogen is usually close to bone dry, the chances of free water in that vessel is about nil. You want to make sure that any free water in low points has been blown out.

 

[jharris3]

you could also suggest pulling a dew point on it to support the suggestion of TD2K. Prove its dry and sealed.

 

[zeusfaber]

Or ask the customer how much oxygen he'll put up with, and what dewpoint he wants.

Bear in mind that the main aim of introducing the nitrogen is to prevent the cylinder breathing in atmospheric moisture during long term storage. Provided the dewpoint stays low enough to preclude the formation of free water in the bottle under all foreseeable storage conditions, the nitrogen doesn't have to be magnificently pure for you to get the corrosion benefit.

Our main check on removing nitrogen blanketed cylinders from long term storage is to make sure that they are still pressurised (without getting too hung-up on the composition of what's in there)

A.

 

[unclesyd]

And there is always the Vapor Phase Inhibitor Package from companies like Cortec.

 

[jamesl]

There is no need to ask for pure nitrogen. We have shipped vessels with Dry Air purge before.

With N2 purge, make sure the supplier put warning signs next to manways and large nozzles. You don't want someone open one manway and just get inside the vessel without realizing these is no oxygen inside.

 

[rmw]

I wouldn't recommend pulling a vacuum to remove the air unless the vessel is rated for full vacuum.

I think Zeusfaber nailed it - the purpose being to prevent the vessel from 'breathing' rather than producing an oxygen free atmosphere, unless of course, that is specified per se. If it is so specified, then the fun of getting there begins.

rmw

 

[jamesl]

rmv,

I don't see anyone here suggesting pulling a vacuum. It is all about replacing the atmospheric air inside the vessel with either nitrogen or very dry air. The vessel will be pressurized to 2 psig-5 psig or even higher, not vacuum.

 

[zeusfaber]

I don't see anyone here suggesting pulling a vacuum

.

No, but I imagine it went through everybody's mind - "remove then replace" being, in principle, a quicker strategy for getting rid of a contaminant than "dilute and discard again and again" - provided it doesn't make your world collapse around you.

A.

 

[rmw]

Jamesl, if you will read the second post very carefully you will be enlightened.

rmw

 

[cloa]

How about purge with a second highly dense gas like SF6 then with Nitrogen- easier to separate.

 

[REGRUMBLE]

Thanks to all for the input. The pressure vessel is designed for full vacuum so that could be done but I do not believe it is necessary. They want the interior to be fully blasted and the nitrogen is only to prevent internal rusting during storage. They are suggesting that we insert nitrogen into the lower end and monitor the air that is escaping using a standard air monitor. When the oxygen level on the exit air drops to near zero the vessel must contain only nitrogen. Then we will increase the pressure to 5 psi. And close the valves.