Zinc and the additives used in the galvanizing, especially Bismuth & Tin form a low melting point eutectoid that wets the grain boundary surfaces. This eutectoid reduces the energy required to "unzips" i.e. crack the steel while in the dip kettle.
From page 35 NYRSTAR Half Year Report 2008 report
"Galveco
Galveco is a patent-protected zinc alloy used for galvanising steel. Between June 2000 and March 2007, Umicore produced and supplied (approximately) 45Kt of Galveco to galvanisers in various countries (corresponding to approximately 3.5Mt of steel that
has been galvanised with Galveco). Umicore withdrew Galveco from the market in March 2007 as a precautionary measure following the discovering of cracking in steel that had been hot dip galvanised. It is alleged that a cause of this cracking is the
use of Galveco."
Influence of Various Parameters on Steel Cracking During Galvanizing
(Presented at the AGA TechForum 2003 in Kansas, MO)
Graham Poag and John Zervoudis
Teck Cominco Metals Ltd.
Product Technology Centre
"When levels of tin or bismuth exceeded approximately 0.2%, the size of cracks
became greater than those obtained in samples from a PW bath, often exceeding
1 in. (25.4 mm) in length. As tin levels increased above 0.3%, crack size
continued to increase, whereas the extent of cracking did not seem to increase
further as bismuth levels increased above 0.2%. "
Current Knowledge of the Cracking of Steels During Galvanizing
A Review of Bath Alloy Additives and their Impact on the Quality of the Galvanized Coating
Galvanizing Structural Steelwork - An approach to the management of Liquid Metal Assisted Cracking
Richard