You are loading Catia model and want to improve the tolerances , - Of the Catia data ?
The imported surface will have a tolerance, but it does not "do anything" since it's not "connected" to any defining data.
i.e IF you create , say , a surface in NX using some curves, the tolerance is the approximation tolerance surface-to-curve, the surface will be created within the tolerance from the curve. If you later change that tolerance of this surface NX will rebuild the surface . An imported surface has no such relation.
Regards,
Tomas